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Docs:
You can access the Spectrum web services at the following locations:
Service
Service Description
Home
WSDL
Search
Use this service to query the existing spectrum catalog and retrieve flux values vs. wavelengths. Output: SOAP XML
search.asmx
wsdl
Util
Use this service to perform operations on spectra, such as resampling and normalization.
util.asmx
Admin
Use this service to create, modify and delete your own spectra from a client application.
Note: this points to the local MySpectrum Service at JHU.
admin.asmx
Every tool published on these pages may be also accessed programmatically via XML Web Services. We recommend you try the VO way and test drive our webservices and take advantage of them to automate (for example) the upload of large amount of spectra. Read the tutorial here to get started. For more details visit http://msdn.microsoft.com/webservices/ , http://java.sun.com/webservices/ and http://www.mono-project.com
You can learn more about web services from the NVO Summer School proceedings: http://www.us-vo.org/summer-school/2004/proceedings/index.cfm